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Posted on December 27, 2015 in Uncategorized
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Based on an analysis of galvanic corrosion research, the research reported herein was formulated to examine the measurement of polarisation curves for Mg to develop a methodology whereby reliable polarisation curves can be measured for Mg. Cathodic polarisation curves were measured for high purity Mg in 3.5% NaCl saturated with Mg(OH)2 using three specimen types: (i) mounted specimens, (ii) specimens hung by fishing line and (iii) plug in specimens. Cathodic polarisation curves were evaluated to yield the corrosion current density icorr and the corresponding corrosion rate Pi, which was compared with the corrosion rate evaluated from hydrogen evolution measurements, PH, and the corrosion rate evaluated by weight loss measurements, PW. Mounted specimens produced values of corrosion rate, Pi, three times larger than values of corrosion rate, Pi, for plug in specimens, attributed to crevice corrosion in the mounted specimens. Crevice corrosion in Mg is totally unexpected from prior research. The plug in specimen configuration was designed to have no crevice and to allow simultaneous measurement of PH and Pi; Pi was consistently less than PH and indicated an apparent valence for Mg of 1.45 in support of the Mg corrosion mechanism involving the uni positive Mg+ ion. The plug in specimen has advantages for the study of Mg corrosion. 2010 Elsevier Ltd.
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Posted on October 17, 2015 in Uncategorized
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Posted on September 7, 2015 in Uncategorized
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Posted on June 15, 2015 in Uncategorized
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